Tribology research is aimed for desirable frictional characteristic; especially in rolling/sliding of polymer-metal contacts which helps smooth operations and energy savings. Conventional roll-slip tests for few million cycles have significant deposit of polymer transfer layer on counterface, thus having a polymer-polymer contact instead of polymer-metal contact. Besides, backtransfer affecting the friction force was never explored. Studying these phenomenon individually and characterizing frictional property without the presence of transfer layer helps for a better understanding of the combined system. A new procedure for measuring friction torque at 20% slip ratio is adapted for varying speeds from 10 to 500 rpm. The observed friction-force increases rapidly at low-speeds and becomes linear at high-speeds. The micrographs of the contact surface prove no trace of transfer layer was found in the newly developed measuring process. Also specimen surface temperature never reached the effective level to affect friction properties.